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Pearls are formed by living organisms, when an irritant enters a mollusc, typically an oyster, it is coated with layers of nacre, this is the same luminous substance that is on the inside. Most material © 2005, 1997, 1991 by penguin random. It's this iridescent coating that gives pearls their signature.

A smooth, hard substance forming a layer inside the shells of some sea creatures A hard, iridescent substance that forms the inner layer of certain mollusk shells, used for making buttons, beads, etc. Now, scientists have finally figured out just how the minuscule layers of this pearlescent.

Via french from old italian naccara, from arabic naqqārah shell, drum]

There are two meanings listed in oed's entry for the noun nacre, one of which is labelled obsolete See ‘meaning & use’ for definitions, usage, and quotation evidence.